基本信息 |
|
| 产品名称： | 双(1,5-环辛二烯)镍(0) |
| CAS： | 1295-35-8 |
| 中文同义词： | 双（1,5环辛二烯）的镍（0） ; 双(1,5-环辛二烯)镍(0) ; 双(1,5-环辛二烯)镍 |
| 英文同义词： | NI(COD)2 ; BIS(1,5-CYCLOOCTADIENE)NICKEL ; CYCLOOCTA-1,5-DIENE, NICKEL ; BIS(1,5-CYCLOOCTADIENE)NICKEL(0) ; BIS(CYCLOOCTADIENE)NICKEL ; NICKEL(COD)2 |
| MDL号： | MFCD00058902 |
| 氢键受体数量： | 0 |
| 氢键供体数量： | 0 |
| Smile： | C/1C/C=C\CC/C=C1.C/1C/C=C\CC/C=C1.[Ni] |
| InChi： | InChI=1S/2C8H12.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;/b2*2-1-,8-7-; |
| InChiKey： | InChIKey=JRTIUDXYIUKIIE-KZUMESAESA-N |
性质 |
|
| 熔点： | 60 DEG C (DEC)(LIT)/60 °C |
| 注解： | APPLICATION: CATALYST FOR THE CYCLOADDITION OF 1,3-DIENES APPLICATION: REACTANT FOR: OXIDATIVE ADDITION REACTIONS. CATALYST FOR: ASYMMETRIC ALPHA-ARYLATION AND HETEROARYLATION OF KETONES WITH CHLOROARENES. CROSS-COUPLING REACTIONS. REGIOSELECTIVE AND STEREOSELECTIVE CARBOXYLATION/CYCLIZATION OF ALLENYL ALDEHYDES UNDER A CARBON DIOXIDE ATMOSPHERE. METHYL CARBOXYLATION OF HOMOPROPARGYLIC ALCOHOLS. STEREOSELECTIVE BORYLATIVE KETONE-DIENE COUPLING. CYCLOADDITION OF BENZAMIDES WITH INTERNAL ALKYNES APPLICATION: USED TO CATALYZE THE ADDITION OF ALLYL PHENYL SULFIDE TO ALKYNES LEADING TO 1,4-DIENES. THE REACTION WITH TERMINAL ACETYLENES PROCEEDS IN HIGH YIELD AND HIGH SELECTIVITY. A VARIETY OF FUNCTIONAL GROUPS ARE TOLERATED RIDADR: UN 1325 4.1/PG 2 RTECS: QR6135000 STORAGE TEMPERATURE: -20 DEG C UNSPSC: 12352103 WGK: 3 |
安全信息 |
|
| 符号： |
GHS02
GHS08
|
| 信号词： | Danger |
| 危险声明： | H228-H334-H351 |
| 警示性声明： | P210-P261-P281-P342 + P311 |
| 危害码： | F,Xn |
| 风险声明： | R:11-40 |
| 安全声明： | S:36/37 |
| WGK德国： | 3 |
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