基本信息 |
|
| 产品名称： | [双(三氟乙酰氧基)碘]苯 |
| CAS： | 2712-78-9 |
| 中文同义词： | [双(三氟乙酰氧基)碘]苯 ; 双(三氟乙酰氧基)碘苯 ; [二(三氟乙酰氧基)碘]苯 ; 二(三氟乙酰氧基)碘代苯 ; 二(三氟乙酸)碘苯 |
| 英文同义词： | PHENYLIODINE(III)BIS(TRIFLUOROACETATE) ; BIS(TRIFLUORACETOXY)- IODOBENZENE ; BTI ; IODOSOBENZENE BIS(TRIFLUOROACETATE) ; PIFA ; [BIS(TRIFLUOROACETOXY)](PHENYL)IODANE ; [BIS(TRIFLUOROACETOXY)IODO]BENZENE ; IODOBENZENE I,I-BIS(TRIFLUOROACETATE) ; DFAIB |
| MDL号： | MFCD00009672 |
| 氢键受体数量： | 4 |
| 氢键供体数量： | 0 |
| Smile： | c1ccc(cc1)I(OC(=O)C(F)(F)F)OC(=O)C(F)(F)F |
| InChi： | InChI=1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H |
| InChiKey： | InChIKey=PEZNEXFPRSOYPL-UHFFFAOYSA-N |
性质 |
|
| 熔点： | 121-125 DEG C(LIT)/121-125℃ |
| 注解： | APPLICATION: REACTANT OR REAGENT FOR: PUMMERER-LIKE REACTIONS. CHEMOSELECTIVE DEPROTECTION OF DIMETHOXYBENZYL ETHERS. MEDIATING OXIDATIVE CYCLOISOMERIZATION. TOSYLOXYLATION OF ANILIDES APPLICATION: USED FOR THE DIRECT ALPHA-HYDROXYLATION OF KETONES UNDER ACIDIC CONDITIONS. ALSO EMPLOYED AS A P-FLUORINATION REAGENT OF 4-ALKYLPHENOLS IN THE PRESENCE OF HF.PYRIDINE (CAT NO 184225) FOR SYNTHESIS OF 4-FLUOROCYCLOHEXA-2,5-DIENONES.REAGENT FOR THE OXIDATION OF N-ACYLHYDRAZONES TO 1,3,4-OXADIAZOLES. PROMOTES THE CYCLIZATION OF STYRYL AMINES TO N-ALKYL OR N-ARYL INDOLES UNSPSC: 12352100 WGK: 3 |
安全信息 |
|
| 符号： |
GHS07
|
| 信号词： | Warning |
| 危险声明： | H315-H319-H335 |
| 警示性声明： | P261-P305 + P351 + P338 |
| 危害码： | Xi |
| 风险声明： | R:36/37/38 |
| 安全声明： | S:26-36 |
| WGK德国： | 3 |
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