基本信息 |
|
| 产品名称： | 三丁基(1-乙氧基乙烯基)锡 |
| CAS： | 97674-02-7 |
| 中文同义词： | 三丁基(1-乙氧基乙烯)锡 ; 三丁基(1-乙氧基乙烯基)锡 |
| 英文同义词： | (1-ETHOXYVINYL)TRIBUTYLSTANNANE ; 1-ETHOXY-1-(TRIBUTYLSTANNYL)ETHYLENE ; TRIBUTYL(1-ETHOXYVINYL)STANNANE ; 1-ETHOXYVINYL-TRI-N-BUTYLTIN ; 1-ETHOXYVINYLTRIBUTYLTIN ; (1-ETHOXYVINYL)TRI-N-BUTYLSTANNANE ; TRIBUTYL(1-ETHOXYETHENYL)STANNANE ; TRI-N-BUTYL(1-ETHOXYVINYL)TIN ; (1-ETHOXYETHENYL)TRIBUTYLSTANNANE ; TRIBUTYL(1-ETHOXYVINYL)TIN |
| MDL号： | MFCD00010240 |
| 氢键受体数量： | 1 |
| 氢键供体数量： | 0 |
| Smile： | CCCC[Sn](CCCC)(CCCC)C(=C)OCC |
| InChi： | InChI=1S/C4H7O.3C4H9.Sn/c1-3-5-4-2;3*1-3-4-2;/h1,4H2,2H3;3*1,3-4H2,2H3; |
| InChiKey： | InChIKey=HGXJOXHYPGNVNK-UHFFFAOYSA-N |
性质 |
|
| 沸点： | 85-86 DEG C/0.1 MMHG(LIT) |
| 密度： | 1.069g/mLat25°C(lit.) |
| 物理性质： | FLASHPOINT: 113 DEG C FLASHPOINT: 235.4 DEG F REFRACTIVE INDEX: N20/D 1.476(LIT) |
| 注解： | APPLICATION: ELECTROPHILIC METHYL KETONE EQUIVALENT USED IN A RECENT SYNTHESIS OF A 13-OXOPHORBINE (CHLOROPHYLL) FROM THE CORRESPONDING 13-BROMOCHLORIN APPLICATION: REAGENT EMPLOYED IN PALLADIUM-CATALYZED COUPLING REACTIONS WITH SULFOXIDES, ALPHA-HALOETHERS, AND CHLOROCYCLOBUTENONES. ALSO USED TO CONVERT ACID CHLORIDES TO ALPHA-OXYGENATED ENONES GENERAL DESCRIPTION: THIS VINYLSTANNANE UNDERGOES STILLE COUPLING WITH A VINYL TRIFLATE, GIVING, AFTER HYDROLYSIS, AN ALPHA,BETA-UNSATURATED KETONE, THUS ACTING AS AN ACETYL ANION EQUIVALENT RIDADR: UN 2788 6.1/PG 3 UNSPSC: 12352103 WGK: 3 |
安全信息 |
|
| 符号： |
GHS06
GHS08
GHS09
|
| 信号词： | Danger |
| 危险声明： | H301-H315-H319-H372-H400 |
| 警示性声明： | P273-P301 + P310-P305 + P351 + P338-P314 |
| 危害码： | T,N |
| 风险声明： | R:21-25-36/38-48/23/25-50/53 |
| 安全声明： | S:35-36/37/39-45-60-61 |
| WGK德国： | 3 |
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