basic_info |
|
| Product_Name: | (S)-N,N-二甲基-1-[(R)-1',2-双(二苯基膦基)二茂铁基]乙胺 |
| CAS: | 55650-59-4 |
| 中文同义词: | (S)-N,N-二甲基-1-[(R)-1',2-双(二苯基膦基)二茂铁基]乙胺 ; (S)-N,N-二甲基-1-[(R)-1,2-双(二苯基膦)二茂铁]乙基胺 ; (S)-N,N-二甲基-1-[(R)-1',2-双(二苯基膦)二茂铁]乙基胺 |
| EnglishSynonyms: | (S)-(R)-BPPFA ; (S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE ; (+)-(S)-N,N-DIMETHYL-1-[(R)-1′,2-BIS(DIPHENYLPHOSPHINO)FERRO ; (+)-(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE |
| pro_mdlNumber: | MFCD00075283 |
| pro_acceptors: | 1 |
| pro_donors: | 0 |
| pro_smile: | C[C@@H]([C]1[CH][CH][CH][C]1P(c2ccccc2)c3ccccc3)N(C)C.c1ccc(cc1)P(c2ccccc2)[C]3[CH][CH][CH][CH]3.[Fe] |
| InChi: | InChI=1S/C21H23NP.C17H14P.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h4-17H,1-3H3;1-14H;/t17-;;/m0../s1 |
| InChiKey: | InChIKey=VUJPTJYMSBMZOZ-RMRYJAPISA-N |
property |
|
| MeltingPoint: | 138-142 DEG C(LIT)/138-142 °C |
| Comments: | APPLICATION: LIGAND USED IN THE ASYMMETRIC HYDROGENATION OF (Z)-ALPHA-AMIDO-CINNAMIC ACIDS OPTICAL ACTIVITY: [ALPHA]20/D +350 DEG, C = 0.5 IN CHLOROFORM UNSPSC: 12352100 WGK: 3 |
secure_info |
|
| secure_symbol: |
GHS07
|
| secure_signal_word: | Warning |
| secure_risk_stmt: | H302-H312-H315-H319-H332-H335 |
| secure_cautionary_stmt: | P261-P280-P305 + P351 + P338 |
| secure_damage_code: | Xn |
| secure_risk_disclosure_stmt: | R:20/21/22-36/37/38 |
| secure_security_stmt: | S:26-36 |
| secure_wgk_germany: | 3 |
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