basic_info |
|
| Product_Name： | (叔丁氧基羰基甲基)溴化三苯基磷 |
| CAS： | 59159-39-6 |
| 中文同义词： | (叔丁氧基羰基甲基)溴化三苯基磷 |
| EnglishSynonyms： | TRIPHENYL TERT BUTOXYCARBONYL METHYL PHOSPHONIUM BROMIDE ; (TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE ; CARBO-TERT-BUTOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE ; (TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHANIUM BROMIDE |
| pro_mdlNumber： | MFCD00075527 |
| pro_acceptors： | 2 |
| pro_donors： | 0 |
| pro_smile： | CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3.[Br-] |
| InChi： | InChI=1S/C24H26O2P.BrH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1 |
| InChiKey： | InChIKey=ZGLFRTJDWWKIAK-UHFFFAOYSA-M |
property |
|
| MeltingPoint： | 178 DEG C (DEC)(LIT) |
| Comments： | APPLICATION: REACTANT FOR: RHODIUM-CATALYZED ASYMMETRIC HYDROGENATION REACTIONS. WITTIG REACTION. WITTIG METHYLENATION. PREPARATION OF N-(PHENYLMETHYL)-CIS-PYRROLIDINEDIACETIC ACID ESTERS VIA DOUBLE AZA-MICHAEL ADDITION REACTION. STEREOSELECTIVE PREPARATION OF OF ALPHA-FLUORO-ALPHA,BETA-UNSATURATED ESTERS VIA DEPROTONATION, FOLLOWED BY FLUORINATION AND STEREOSELECTIVE WITTIG OLEFINATION WITH ALDEHYDES. WITTIG CHAIN EXTENSION REACTIONS NSC 82468 UNSPSC: 12352100 WGK: 3 |
secure_info |
|
| secure_symbol： |
GHS07
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H315-H319-H335 |
| secure_cautionary_stmt： | P261-P305 + P351 + P338 |
| secure_damage_code： | Xi |
| secure_risk_disclosure_stmt： | R:36/37/38 |
| secure_security_stmt： | S:26-37/39 |
| secure_wgk_germany： | 3 |
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