basic_info |
|
| Product_Name: | (-)-异松蒎基硼烷-四甲基乙二胺络合物 |
| CAS: | 67826-92-0 |
| 中文同义词: | (-)-异松蒎基硼烷-四甲基乙二胺络合物 |
| EnglishSynonyms: | (-)-ISOPINOCAMPHEYLBORANE TMEDA COMPLEX ; (-)-ISOPINO CAMPHEYLBORANE TETRA METHYL ETHYLENEDIAMINE COMPLEX ; (-)-ISOPINOCAMPHENYLBORANE TMEDA COMPLEX ; (-)-N,N'-BIS(MONOISOPINOCAMPHEYLBORANE)-N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE ; (R)-ALPINE-BORAMINE(TM) |
| pro_mdlNumber: | MFCD00077801 |
| pro_acceptors: | 0 |
| pro_donors: | 0 |
| pro_smile: | B[C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.B[C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.CN(C)CCN(C)C |
| InChi: | InChI=1S/2C10H19B.C6H16N2/c2*1-6-8-4-7(5-9(6)11)10(8,2)3;1-7(2)5-6-8(3)4/h2*6-9H,4-5,11H2,1-3H3;5-6H2,1-4H3/t2*6-,7+,8-,9-;/m00./s1 |
| InChiKey: | InChIKey=QNDCJVKDHWRHGS-NCHGFZPDSA-N |
property |
|
| MeltingPoint: | 139-141 DEG C(LIT) |
| Comments: | APPLICATION: CHIRAL HYDROBORATION REAGENT. THIS AMINE-BORANE COMPLEX HAS BEEN USED AS A POLARITY-REVERSAL CATALYST FOR THE KINETIC RESOLUTION OF RACEMIC ESTERS AND KETONES LEGAL INFORMATION: ALPINE-BORAMINE IS A TRADEMARK OF SIGMA-ALDRICH CO LLC RIDADR: UN 2813 4.3/PG 3 UNSPSC: 12352100 WGK: 3 |
secure_info |
|
| secure_symbol: |
GHS02
GHS07
|
| secure_signal_word: | Warning |
| secure_risk_stmt: | H261-H315-H319 |
| secure_cautionary_stmt: | P231 + P232-P305 + P351 + P338-P422 |
| secure_damage_code: | F,Xi |
| secure_risk_disclosure_stmt: | R:15-36/38 |
| secure_security_stmt: | S:26-36-43 |
| secure_wgk_germany: | 3 |
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