(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN ,105251-52-3 _ChemCD

(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN

basic_info
Product_Name：	(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN
CAS：	105251-52-3
EnglishSynonyms：	(1S,9S)-1,9-BIS[[(T-BUTYL)DIMETHYLSILYLOXY]METHYL]-5-CYANOSEMICORRIN ; SEMICORRIN CHIRAL LIGAND 2 ; (1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN ; (1S,9S)-1,9-BIS[(TERT-BUTYLDIMETHYLSILOXY)METHYL]-5-CYANOSEMICORRIN
pro_mdlNumber：	MFCD00142698
pro_acceptors：	5
pro_donors：	1
pro_smile：	CC(C)(C)[Si](C)(C)OC[C@@H]1CC/C(=C(\C#N)/C2=N[C@@H](CC2)CO[Si](C)(C)C(C)(C)C)/N1
InChi：	InChI=1S/C24H45N3O2Si2/c1-23(2,3)30(7,8)28-16-18-11-13-21(26-18)20(15-25)22-14-12-19(27-22)17-29-31(9,10)24(4,5)6/h18-19,26H,11-14,16-17H2,1-10H3/b21-20-/t18-,19-/m0/s1
InChiKey：	InChIKey=JYNLYWZVXIGLJC-GLHDQHDCSA-N
property
MeltingPoint：	74-77 DEG C
Comments：	OPTICAL ACTIVITY: [ALPHA]20/D -63+/-2 DEG, C = 1% IN CHLOROFORM OTHER NOTES: THE CU(II) AND CO(II) COMPLEXES ARE CATALYSTS FOR ENANTIOSELECTIVE CYCLOPROPANATION AND REDUCTION REACTIONS STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352100 WGK: 3
secure_info
secure_symbol：	GHS07
secure_signal_word：	Warning
secure_risk_stmt：	H315-H319-H335
secure_cautionary_stmt：	P261-P305 + P351 + P338
secure_damage_code：	Xi
secure_risk_disclosure_stmt：	R:36/37/38
secure_security_stmt：	S:26-36
secure_wgk_germany：	3

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