基本信息 |
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| 产品名称： | 1-叔丁基-4,4,4-三(二甲氨基)-2,2-二[三(二甲氨基)-正膦亚基氨基]-2Λ5,4Λ5-连二(磷氮基化合物) |
| CAS： | 111324-04-0 |
| 中文同义词： | 1-叔丁基-4,4,4-三(二甲氨基)-2,2-二[三(二甲氨基)-正膦亚基氨基]-2Λ5,4Λ5-连二(磷氮基化合物) |
| 英文同义词： | PHOSPHAZENE BASE P4-T-BU ; 1-TERT-BUTYL-4,4,4-TRIS(DIMETHYLAMINO)-2,2-BIS[TRIS(DIMETHYLAMINO)-PHOSPHORANYLIDENAMINO]-2LAMBDA5,4LAMBDA5-CATENADI(PHOSPHAZENE) |
| MDL号： | MFCD00145114 |
| 氢键受体数量： | 13 |
| 氢键供体数量： | 0 |
| Smile： | CC(C)(C)N=P(N=P(N(C)C)(N(C)C)N(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C |
| InChi： | InChI=1S/C22H63N13P4/c1-22(2,3)23-36(24-37(27(4)5,28(6)7)29(8)9,25-38(30(10)11,31(12)13)32(14)15)26-39(33(16)17,34(18)19)35(20)21/h1-21H3 |
| InChiKey： | InChIKey=NSRBCQCXZAYQHF-UHFFFAOYSA-N |
性质 |
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| 密度： | DENSITY: 0.90 G/ML AT 20 DEG C |
| 物理性质： | FLASHPOINT: -14.8 DEG F FLASHPOINT: -26 DEG C |
| 注解： | APPLICATION: PHOSPHAZENE BASES: A FAMILY OF EXTREMELY STRONG, NON-IONIC, NON-CHARGED NITROGEN-BASES CAUTION: PRODUCT CRYSTALLIZES OUT OF SOLUTION, CAN BE REDISSOLVED ON HEATING TO 40 DEG C CONCENTRATION: APPROX 1.0 M IN HEXANE FORM: SOLUTION OTHER NOTES: BASE FOR ENOLATE FORMATION AND STEREOSELECTIVE ALKYLATION OTHER NOTES: EXTREMELY STRONG, HINDERED, NEUTRAL NITROGEN BASE OTHER NOTES: IT IS ABOUT 1018 TIMES MORE BASIC THAN DBU [PKA (DMSO) 30.25]. STABLE TO HYDROLYSIS AND UNAFFECTED BY ALKYLATING AGENTS RIDADR: UN 2924 3/PG 2 UNSPSC: 12352100 WGK: 3 |
| 浓度： | APPROX 1.0 M IN HEXANE |
安全信息 |
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| 符号： |
GHS02
GHS05
GHS07
GHS08
|
| 信号词： | Danger |
| 危险声明： | H225-H304-H314-H336-H361f-H373-H412 |
| 警示性声明： | P210-P261-P273-P280-P301 + P310-P305 + P351 + P338 |
| 危害码： | F,C |
| 风险声明： | R:11-34-48/20-52/53-62-65-67 |
| 安全声明： | S:16-26-36/37/39-45-61-62 |
| WGK德国： | 3 |
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