基本信息 |
|
| 产品名称： | (三氟甲基)三甲基硅烷 [三氟甲基化试剂] |
| CAS： | 81290-20-2 |
| 中文同义词： | 三甲基(三氟甲基)硅烷 ; 三甲基三氟甲基硅 ; (三氟甲基)三甲基硅烷 ; (三氟甲基)三甲基硅烷 [三氟甲基化试剂] ; 三氟甲基三甲基硅烷 |
| 英文同义词： | (TRIMETHYLSILYL)TRIFLUOROMETHANE ; RUPPERT'S REAGENT ; (TRIFLUOROMETHYL)-TRIMETHYLSILAN ; TTMS ; TMS-CF3 ; TRIMETHYL(TRIFLUOROMETHYL)SILANE ; (TRIFLUOROMETHYL)TRIMETHYLSILANE ; RUPPERT-PRAKASH REAGENT ; TFMTMS |
| MDL号： | MFCD00145454 |
| 氢键受体数量： | 0 |
| 氢键供体数量： | 0 |
| Smile： | C[Si](C)(C)C(F)(F)F |
| InChi： | InChI=1S/C4H9F3Si/c1-8(2,3)4(5,6)7/h1-3H3 |
| InChiKey： | InChIKey=MWKJTNBSKNUMFN-UHFFFAOYSA-N |
性质 |
|
| 沸点： | 45 DEG C/40 °C/40 °C |
| 密度： | 0.962g/mLat20°C(lit.) |
| 物理性质： | FLASHPOINT: -17 DEG C FLASHPOINT: 1.4 DEG F REFRACTIVE INDEX: N20/D 1.386 |
| 注解： | APPLICATION: REACTANT FOR: SILVER-MEDIATED C-H TRIFLUOROMETHYLATION OF ARENES. PREPARATION OF TRIFLUOROMETHYL KETONE ANALOG OF L-ARGININE HAVING CONTRASTING INHIBITORY ACTIVITY AGAINST HUMAN ARGINASE I AND HISTONE DEACETYLASE 82. ORGANOCATALYZED REGIO- AND ENANTIOSELECTIVE ALLYLIC TRIFLUOROMETHYLATION OF MORITA-BAYLIS-HILLMAN ADDUCTS. PALLADIUM-CATALYZED OXIDATIVE TRIFLUOROMETHYLATION OF INDOLES. PREPARATION OF 5-HT1A ANTAGONISTS. USED AS DIFLUOROCARBENE SOURCE CONCENTRATION: APPROX 2.0 M IN THF FORM: SOLUTION RIDADR: UN 1993 3/PG 2 UNSPSC: 12352100 WGK: 3 |
| 浓度： | 0.5MinTHF |
安全信息 |
|
| 符号： |
GHS02
|
| 信号词： | Danger |
| 危险声明： | H225 |
| 警示性声明： | P210 |
| 危害码： | F |
| 风险声明： | R:11 |
| 安全声明： | S:16-33 |
| UN代码： | 1993 |
| WGK德国： | 3 |
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