基本信息 |
|
| 产品名称： | 三苯基膦-氢化铜六聚物 |
| CAS： | 33636-93-0 |
| 中文同义词： | 三苯基膦-氢化铜六聚物 ; 三苯基磷酸亚酮六聚体 |
| 英文同义词： | TRIPHENYLPHOSPHINE COPPER(I) HYDRIDE ; TRIPHENYLPHOSPHINE-COPPER(I) HYDRIDE HEXAMER ; HYDRIDO(TRIPHENYLPHOSPHINE)COPPER(I) HEXAMER ; CUPROUS HYDRIDE TRIPHENYLPHOSPHINE HEXAMER ; STRYKER'S REAGENT ; (TRIPHENYLPHOSPHINE)COPPER HYDRIDE HEXAMER |
| MDL号： | MFCD00221518 |
| 氢键受体数量： | 0 |
| 氢键供体数量： | 0 |
| Smile： | c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.[CuH].[CuH].[CuH].[CuH].[CuH].[CuH] |
| InChi： | InChI=1S/6C18H15P.6Cu.6H/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;;;;;;;/h6*1-15H;;;;;;;;;;;; |
| InChiKey： | InChIKey=PYHLOCIDGQNZFY-UHFFFAOYSA-N |
性质 |
|
| 注解： | APPLICATION: CATALYST FOR: CONJUGATE REDUCTION OF ORTHO-SUBSTITUTED CINNAMIC ESTERS TO FORM COPPER ENOLATES. CHEMOSELECTIVE PREPARATION OF ALCOHOLS VIA HYDROGENATION OF ALDEHYDES. 1,2-ADDITION/TRANSMETALATION REACTIONS. SYNTHESIS OF MONOMER FOR PREPARATION OF PHOSPHORUS- AND SILICON-CONTAINING EPOXY RESINS. HYDROSILYLATION REACTIONS. CHIRAL HYDROGENATION REACTIONS. HYDROSTANNATION OF ACTIVATED ALKYNES APPLICATION: USEFUL SYNTHETIC APPLICATIONS INCLUDE STOICHIOMETRIC AND CATALYTIC HYDROGENATIONS, CHEMOSELECTIVE CONJUGATE REDUCTIONS, AS WELL AS REGIOSPECIFIC AND STEREOSELECTIVECONJUGATE HYDRIDE REDUCTIONS UNSPSC: 12352103 WGK: 3 |
安全信息 |
|
| 符号： |
GHS07
|
| 信号词： | Warning |
| 危险声明： | H315-H319-H335 |
| 警示性声明： | P261-P305 + P351 + P338 |
| 危害码： | Xi |
| 风险声明： | R:36/37/38 |
| 安全声明： | S:26-36 |
| WGK德国： | 3 |
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