(三苯基亚正膦基)乙腈 ,16640-68-9

(三苯基亚正膦基)乙腈

基本信息
产品名称：	(三苯基亚正膦基)乙腈
CAS：	16640-68-9
中文同义词：	(三苯基亚正膦基)乙腈 ; 氰亚甲基三苯基膦 ; (三苯基膦)乙腈
英文同义词：	(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE ; (CYANOMETHYLENE)TRIPHENYLPHOSPHORANE ; 2-(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE ; CYANOMETHYLTRIPHENYLPHOSPHONIUM YLIDE ; (CYANO)(TRIPHENYLPHOSPHORANYLIDENE)METHANE
MDL号：	MFCD00567633
氢键受体数量：	1
氢键供体数量：	0
Smile：	c1ccc(cc1)P(=CC#N)(c2ccccc2)c3ccccc3
InChi：	InChI=1S/C20H16NP/c21-16-17-22(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-15,17H
InChiKey：	InChIKey=APISVOVOJVZIBA-UHFFFAOYSA-N
性质
熔点：	189-195 DEG C(LIT)
注解：	APPLICATION: REACTANT FOR . PREPARATION OF ANTITRYPANOSOMAL ACTIVITY. DIRECT MICHAEL ADDITION OF ALKENES. SYNTHESIS OF 1,6-ENYNES. BETA-UMPOLUNG ADDITION OF NUCLEOPHILES TO ACTIVATED DISUBSTITUTED ALKYL ALLENES. STEREOSELECTIVE ANALYSIS OF BETA-HOMOPROLINE DERIVATIVES. STEREOSELECTIVE OLEFINATION OF N-SULFONYL IMINES. PALLADACYCLE MEDIATED SYNTHESIS OF CYANO-FUNCTIONALIZED CHIRAL DIPHOSPHINES. HORNER-WADSWORTH-EMMONS REACTIONS APPLICATION: WITTIG REAGENT FOR THE PREPARATION OF ALPHA,BETA, UNSATURATED NITRILES FROM CARBONYL COMPOUNDS NSC 135204 UNSPSC: 12352103 WGK: 3
安全信息
符号：	GHS07
信号词：	Warning
危险声明：	H315-H319-H335
警示性声明：	P261-P305 + P351 + P338
危害码：	Xi
风险声明：	R:36/37/38
安全声明：	S:26-36
WGK德国：	3

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