基本信息 |
|
| 产品名称： | 苯基次甲基-二(三环己基膦基)-二氯化钌 |
| CAS： | 172222-30-9 |
| 中文同义词： | 苯基次甲基-二(三环己基膦基)-二氯化钌 ; 二(三环己基膦)亚苄基二氯化钌 |
| 英文同义词： | GRUBB'S CATALYST, 97% ; RUTHENIUM,DICHLORO(PHENYLMETHYLENE)BIS (TRICYCLOHEXYLPHOSPHINE) ; BIS(TRICYCLOHEXYLPHOSPHINE) BENZYLIDINE RUTHENIUM(IV) CHLORIDE ; BENZYLIDENE-BIS(TRICYCLOHEXYLPHOSPHINE)DICHLORORUTHENIUM ; BIS(TRICYCLOHEXYLPHOSPHINE)BENZYLIDINE RUTHENIUM(IV) DICHLORIDE ; GRUBBS CATALYST ; GRUBBS CATALYST, 1ST GENERATION ; GRUBBS'S CATALYST |
| MDL号： | MFCD01090946 |
| 氢键受体数量： | 0 |
| 氢键供体数量： | 0 |
| Smile： | C=Cc1ccccc1.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.Cl[Ru]Cl |
| InChi： | InChI=1S/2C18H33P.C8H8.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-8-6-4-3-5-7-8;;;/h2*16-18H,1-15H2;2-7H,1H2;2*1H;/q;;;;;+2/p-2 |
| InChiKey： | InChIKey=IEEOQDKBWLBRKR-UHFFFAOYSA-L |
性质 |
|
| 熔点： | 153 DEG C (DEC)(LIT)/153℃ |
| 注解： | APPLICATION: GRUBBS 1ST GENERATION CATALYST. FIRST METATHESIS CATALYST TO BE WIDELY USED IN ORGANIC SYNTHESIS. USEFUL IN RING-OPENING METATHESIS POLYMERIZATION (ROMP) OF STRAINED CYCLIC OLEFINS, IN OLEFIN CROSS METATHESIS (CM) AND RING CLOSING METATHESIS (RCM) OF TERMINAL OLEFINS UNDER A VARIETY OF REACTIONS CONDITIONS, AND ETHENOLYSIS OF INTERNAL OLEFINS APPLICATION: METATHESIS: RUTHENIUM-BASED METATHESIS CATALYSTSHYDROSILYLATION CATALYSTS LEGAL INFORMATION: US PATENT NO 6,111,121 AND FOREIGN EQUIVALENTS APPLY. SALE OF THIS PRODUCT CONVEYS TO THE BUYER A LIMITED-USE RESEARCH LICENSE. FOR FULL DETAILS OF THIS LICENSE PLEASE SEE SIGMA-ALDRICH.COM/MATERIALICENSE. FOR QUESTIONS, PLEASE CONTACT US AT ALDRICH AT SIAL.COM OR MATERIA AT INFO AT MATERIA-INC.COM OTHER NOTES: NO BULK ORDERS STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3 |
安全信息 |
|
| 符号： |
GHS02
GHS07
|
| 信号词： | Warning |
| 危险声明： | H228-H315-H319-H335 |
| 警示性声明： | P210-P261-P305 + P351 + P338 |
| 危害码： | F,Xi |
| 风险声明： | R:11-36/37/38 |
| 安全声明： | S:26-36 |
| WGK德国： | 3 |
* If the product has intellectual property rights, a license granted is must or contact us.
2010-2025 © Chemical Cloud Database. ALL Rights Reserved.浙ICP备11020424号-1
浙公网安备 33010802004002号
English
