基本信息 |
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| 产品名称： | (2S,4S)-1-Boc-4-二苯基膦-2-(二苯基膦甲基)吡咯烷 |
| CAS： | 61478-28-2 |
| 中文同义词： | (2S,4S)-1-Boc-4-二苯基膦-2-(二苯基膦甲基)吡咯烷 ; (2S, 4S)-4-二苯基膦-2-(二苯基膦甲基)-1-特丁氧羰基吡咯烷 ; (2S,4S)-1-Boc-4-二苯基膦-2-(二苯基膦甲基)吡咯烷 |
| 英文同义词： | (2S,4S)-1-TERT-BUTOXYCARBONYL-4-DIPHENYLPHOSPHINO-2-(DIPHENYLPHOSPHINOMETHYL)PYRROLIDINE ; (2S,4S)-(-)-1-BOC-4-DIPHENYLPHOSPHINO-2-(DIPHENYLPHOSPHINOMETHYL)PYRROLIDINE ; (-)-BPPM ; (2S,4S)-1-BOC-4-DIPHENYLPHOSPHINO-2-(DIPHENYLPHOSPHINOMETHYL)PYRROLIDINE ; (2S,4S)-N-BUTOXYCARBONYL-4-DIPHENYLPHOSPHINO-2-(DIPHENYLPHOSPHINOMETHYL)PYRROLIDINE ; S,S-BPPM ; (2S,4S)-(-)-N-BOC-4-DIPHENYLPHOSPHINO-2-DIPHENYLPHOSPHINOMETHYL-PYRROLIDINE ; (2S,4S)-(-)-1-TBOC-4-DIPHENYLPHOSPHINO-2-(DIPHENYLPHOSPHINOMETHYL)PYRROLIDINE ; (2S,4S)-(-)-2-(DIPHENYLPHOSPHINOMETHYL)-4-(DIPHENYLPHOSPHINO)-N-(T-BUTOXYCARBONYL)PYRROLIDINE ; (2S,4S)-BPPM ; (2S, 4S)-4-(DIPHENYLPHOSPHINO)-2-[(DIPHENYLPHOSPHINO) METHYL]-1-(T-BUTOXYCARBONYL) PYRROLIDINE ; BPPM |
| MDL号： | MFCD01631275 |
| 氢键受体数量： | 3 |
| 氢键供体数量： | 0 |
| Smile： | CC(C)(C)OC(=O)N1C[C@H](C[C@H]1CP(c2ccccc2)c3ccccc3)P(c4ccccc4)c5ccccc5 |
| InChi： | InChI=1S/C34H37NO2P2/c1-34(2,3)37-33(36)35-25-32(39(30-20-12-6-13-21-30)31-22-14-7-15-23-31)24-27(35)26-38(28-16-8-4-9-17-28)29-18-10-5-11-19-29/h4-23,27,32H,24-26H2,1-3H3/t27-,32-/m0/s1 |
| InChiKey： | InChIKey=BFMKBYZEJOQYIM-UCGGBYDDSA-N |
性质 |
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| 熔点： | 96-100 DEG C |
| 注解： | ASSAY METHOD: SUM OF ENANTIOMERS, HPLC OPTICAL ACTIVITY: [ALPHA]20/D -39+/-2 DEG, C = 1% IN BENZENE ORIGINAL SKU: 20424-250MG-F OTHER NOTES: CHIRAL PHOSPHINE LIGAND FOR THE RHODIUM CATALYZED ASYMMETRIC HYDROGENATION OF OLEFINS AND KETONES. ALPHA-AMINO ACIDS ARE OBTAINED IN VERY HIGH OPTICAL PURITY 1 OTHER NOTES: HYDROFORMYLATION OTHER NOTES: HYDROGENATION OF KETONES TO ALCOHOLS STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352100 WGK: 3 |
安全信息 |
|
| 符号： |
GHS07
|
| 信号词： | Warning |
| 危险声明： | H315-H319-H335 |
| 警示性声明： | P261-P305 + P351 + P338 |
| 危害码： | Xi |
| 风险声明： | R:36/37/38 |
| 安全声明： | S:26-36 |
| WGK德国： | 3 |
| 闪点： | 89 °C |
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