basic_info |
|
| Product_Name： | (S,S)-雅可布逊催化剂氯化锰络合物 |
| CAS： | 135620-04-1 |
| 中文同义词： | (1S,2S)-(+)-(1,2-环己烷二氨基-N,N′-双(3,5-二丁基亚水杨基)锰(Ⅲ)氯化物 ; (S,S)-雅可布逊催化剂氯化锰络合物 |
| EnglishSynonyms： | (1S,2S)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE ; (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE(III) CHLORIDE ; (S,S)-(+)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE ; (S,S)-JACOBSEN CAT ; (S,S)-JACOBSEN CATALYST ; (S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX ; (S,S)-JACOBSEN'S CATALYST ; (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE |
| pro_mdlNumber： | MFCD02101663 |
| pro_acceptors： | 4 |
| pro_donors： | 0 |
| pro_smile： | CC(C)(C)c1cc\2c(c(c1)C(C)(C)C)O[Mn](Oc3c(cc(cc3C(C)(C)C)C(C)(C)C)/C=N/[C@H]4CCCC[C@@H]4/N=C2)Cl |
| InChi： | InChI=1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1 |
| InChiKey： | InChIKey=LJVAWOSDJSQANR-RUIQGICGSA-K |
property |
|
| MeltingPoint： | 330-332 DEG C(LIT) |
| Comments： | APPLICATION: SALEN (MN)-CATALYZED ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS. HIGH ENANTIOSELECTIVITIES AND YIELDS ARE OBTAINED FOR A VARIETY OF SUBSTRATES, ESPECIALLY CIS-ALKENES. A FEW APPLICATIONS INCLUDE THE SYNTHESIS OF THE TAXOL SIDE CHAIN10 AND CIS-1-AMINO-2-INDANOL. JACOBSEN'S CATALYST HAS ALSO BEEN USED IN THE ASYMMETRIC ALPHA-HYDROXYLATION OF SILYL ENOL ETHERS. CATALYST FOR THE ENANTIOSELECTIVE EPOXIDATION OF A VARIETY OF OLEFINS LEGAL INFORMATION: MANUFACTURED UNDER LICENSE BY SHASUN CHEMICALS AND DRUGS LIMITED, USING JACOBSEN HKR TECHNOLOGY UNSPSC: 12352100 WGK: 3 |
secure_info |
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| secure_symbol： |
GHS07
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H315-H319-H335 |
| secure_cautionary_stmt： | P261-P305 + P351 + P338 |
| secure_damage_code： | Xi |
| secure_risk_disclosure_stmt： | R:36/37/38 |
| secure_security_stmt： | S:26-36 |
| secure_wgk_germany： | 3 |
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