basic_info |
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| Product_Name： | (R)-(+)-(6,6'-二甲氧基联苯-2,2'-基)双(二苯基膦) |
| CAS： | 133545-16-1 ;133545-17-2 ;145209-26-3 |
| 中文同义词： | (R)-(+)-2,2'-二(二苯基膦)-6,6'-二甲氧基-1,1'-联苯 ; (S)-(-)-(6,6'-二甲氧基联苯-2,2'-基)双(二苯基膦) ; (S)-(-)-2,2'-二(二苯基膦)-6,6'-二甲氧基-1,1'-联苯 ; (R)-(+)-(6,6'-二甲氧基联苯-2,2'-基)双(二苯基膦) |
| EnglishSynonyms： | (S)-PPHENYL-MEOBIPHEP ; (R)-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL ; 2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIHYDROXYBIPHENYL,(R)-FORM,DI-ME ETHER ; (RS)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE) ; (R)-MEO-BIPHEP ; (S)-MEO-BIPHEP ; (S)-(-)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE) ; (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL ; (R)-(+)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE) ; (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL ; SL-A101-1 ; SL-A101-2 ; (S)-(-)-MEO-BIPHEP ; (R)-(+)-MEO-BIPHEP |
| pro_mdlNumber： | MFCD03095430 |
| pro_acceptors： | 2 |
| pro_donors： | 0 |
| pro_smile： | COc1cccc(c1c2c(cccc2P(c3ccccc3)c4ccccc4)OC)P(c5ccccc5)c6ccccc6 |
| InChi： | InChI=1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3 |
| InChiKey： | InChIKey=KRJVQCZJJSUHHO-UHFFFAOYSA-N |
property |
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| Comments： | APPLICATION: ATROPISOMERIC DIPHOSPHINE APPLICATION: ATROPISOMERIC MEOBIPHEP LIGANDS. HYDROGENATION OF ALPHA- AND BETA-FUNCTIONALIZED KETONES. HYDROGENATION OF HETEROARENES. C-C COUPLING REACTIONS APPLICATION: THE PD(0) COMPLEX FOR CYCLIZATION OF HYDROXY ALLYLIC CARBONATES APPLICATION: THE RH(I) COMPLEX IS EMPLOYED FOR HIGHLY ENANTIOSELECTIVE ASYMMETRIC ISOMERIZATION OF ALLYLAMINES TO ENAMINES APPLICATION: THE RU(II) COMPLEX HYDROGENATES BETA-KETO ESTERS IN HIGH ENANTIOSELECTIVITY GENERAL DESCRIPTION: SOLD IN COLLABORATION WITH SOLVIAS AG UNSPSC: 12352100 WGK: 3 |
| Information： | OPTICAL PURITY: EE: =>99% |
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| secure_wgk_germany： | 3 |
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