basic_info |
|
| Product_Name： | 二氯二(三甲基膦)合镍(II) |
| CAS： | 103421-62-1 ;19232-05-4 |
| 中文同义词： | 二氯二(三甲基膦)镍(II) ; 二氯二(三甲基膦)合镍(II) |
| EnglishSynonyms： | BIS(TRIMETHYLPHOSPHINE)NICKEL DICHLORIDE ; DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(II) |
| pro_mdlNumber： | MFCD03412128 |
| pro_acceptors： | 0 |
| pro_donors： | 0 |
| pro_smile： | CP(C)C.CP(C)C.Cl[Ni]Cl |
| InChi： | InChI=1S/2C3H9P.2ClH.Ni/c2*1-4(2)3;;;/h2*1-3H3;2*1H;/q;;;;+2/p-2 |
| InChiKey： | InChIKey=KYHNNWWCXIOTKC-UHFFFAOYSA-L |
property |
|
| MeltingPoint： | 194-199 DEG C(LIT) |
| Comments： | APPLICATION: CATALYST FOR: WENKERT ARYLATION OF THIOPHENE WITH ARYL GRIGNARD REAGENTS. REGIOSELECTIVE [2+2+2] CYCLOADDITION OF CARBORYNE WITH ALKYNES TO GIVE BENZOCARBORANE COMPOUNDS. KUMADA-CORRIU CROSS COUPLING OF GRIGNARD REAGENTS. BORYLATION OF ARYL CHLORIDES. REDUCTIVE ALDOL CYCLIZATION-LACTONIZATION. ARYLCYANATION OF ALKYNES. ALKYNYLATION OF BENZONITRILES VIA C-C BOND ACTIVATION UNSPSC: 12352103 UV ABSORPTION: 244 NM WGK: 3 |
secure_info |
|
| secure_symbol： |
GHS07
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H302-H312-H332 |
| secure_cautionary_stmt： | P280 |
| secure_damage_code： | Xn |
| secure_risk_disclosure_stmt： | R:20/21/22 |
| secure_security_stmt： | S:36/37 |
| secure_wgk_germany： | 3 |
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