1,1-双(苯基亚膦基)二茂铁 ,72954-06-4 _ChemCD

1,1-双(苯基亚膦基)二茂铁

basic_info
Product_Name：	1,1-双(苯基亚膦基)二茂铁
CAS：	72954-06-4
中文同义词：	1,1'-双(苯基亚膦基)二茂铁 ; 1,1-双(苯基亚膦基)二茂铁
EnglishSynonyms：	1,1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE ; 1,1'-(FERROCENEDIYL)PHENYLPHOSPHINE
pro_mdlNumber：	MFCD04974069
pro_acceptors：	0
pro_donors：	0
pro_smile：	c1ccc(cc1)P([C]2[CH][CH][CH][CH]2)[C]3[CH][CH][CH][CH]3.[Fe]
InChi：	InChI=1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChiKey：	InChIKey=HKOUDNXXOXEYNZ-UHFFFAOYSA-N
property
MeltingPoint：	88-92 DEG C(LIT)
Comments：	APPLICATION: REACTANT FOR PREPARATION OF MACROCYCLIC TRIDENTATE FERROCENYLPHOSPHINE LIGANDS. PREPARATION OF PHOSPHORUS-BRIDGED FERROCENOPHANE WITH SYN AND ANTI CONFORMATIONS. REACTION WITH PHENYLLITHIUM AND CHLOROPHOSPHINE TO GIVE FERROCENEDIYL LIGAND AND ITS RHODIUM COMPLEX CATALYST FOR SELECTIVE HYDROFORMYLATION OF ALKENES. RING-OPENING REACTIONS VIA RING SLIPPAGE. PREPARATION OF PALLADIUM CHLORO (FERROCENE-BRIDGED)PHOSPHINE-PHOSPHONITE COMPLEX FOR CATALYSIS OF HECK REACTION OF IODOBENZENE WITH ME ACRYLATE STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3
secure_info
secure_wgk_germany：	3

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