2,6-双[(3aR,8aS)-(+)-8H-茚[1,2-d]恶唑啉-2-基]吡啶 ,357209-32-6 _ChemCD

2,6-双[(3aR,8aS)-(+)-8H-茚[1,2-d]恶唑啉-2-基]吡啶

basic_info
Product_Name：	2,6-双[(3aR,8aS)-(+)-8H-茚[1,2-d]恶唑啉-2-基]吡啶
CAS：	357209-32-6
中文同义词：	2,6-双[(3aR,8aS)-(+)-8H-茚[1,2-d]恶唑啉-2-基]吡啶
EnglishSynonyms：	2,6-BIS[(3AR,8AS)-(+)-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE ; (3AR,3'AR,8AS,8'AS)-2,2'-(2,6-PYRIDINEDIYL)BIS3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE ; (3AR,8AS)-IN-PYBOX
pro_mdlNumber：	MFCD09265074
pro_acceptors：	5
pro_donors：	0
pro_smile：	c1ccc2c(c1)C[C@H]3[C@@H]2N=C(O3)c4cccc(n4)C5=N[C@@H]6c7ccccc7C[C@@H]6O5
InChi：	InChI=1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m0/s1
InChiKey：	InChIKey=BZSJUFJXCHHRHW-MYDTUXCISA-N
property
MeltingPoint：	284 DEG C (DEC)
Comments：	APPLICATION: CATALYTIC LIGAND USED FOR: [3+2] CYCLOADDITION OF N-TOSYL AZIRIDINES WITH ELECTRON-RICH ALKENES VIA SELECTIVE CARBON-CARBON BOND CLEAVAGE. ENANTIOSELECTIVE MUKAIYAMA-ALDOL REACTIONS. ENANTIOSELECTIVE CARBONYL-ENE REACTIONS. CU(I)-CATALYZED ASYMMETRIC ALKYNYLATION OF IMINO ESTERS WITH TERMINAL ALKYNES. ASYMMETRIC THREE-COMPONENT COUPLING REACTIONS CATALYZED BY A CU/PYBOX COMPLEX. ENANTIOSELECTIVE DIELS-ALDER REACTION. NI-CATALYZED CROSS-COUPLING REACTIONS OPTICAL ACTIVITY: [ALPHA]20/D +386 DEG, C = 1 IN METHYLENE CHLORIDE(LIT) UNSPSC: 12352100 WGK: 3
secure_info
secure_risk_stmt：	H413
secure_wgk_germany：	3

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