(S)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联-2,2'-萘酚 ,111795-33-6

(S)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联-2,2'-萘酚

基本信息
产品名称：	(S)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联-2,2'-萘酚
CAS：	111795-33-6 ;111822-69-6
中文同义词：	(S)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联-2,2'-萘酚 ; (R)-3,3′-双(三苯甲硅烷基)-1,1′-联-2-萘酚
英文同义词：	(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-NAPHTHOL ; (S)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-NAPHTHOL ; S-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-NAPHTHOL ; (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHALENE-2,2'-DIOL ; (R)-3,3-BIS(TRIPHENYLSILYL)-1,1-BI-2-NAPHTHOL
MDL号：	MFCD09265078
氢键受体数量：	2
氢键供体数量：	2
Smile：	c1ccc(cc1)[Si](c2ccccc2)(c3ccccc3)c4cc5ccccc5c(c4O)c6c7ccccc7cc(c6O)[Si](c8ccccc8)(c9ccccc9)c1ccccc1
InChi：	InChI=1S/C56H42O2Si2/c57-55-51(59(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)58)60(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40,57-58H
InChiKey：	InChIKey=STBZSRVMGWTCOU-UHFFFAOYSA-N
性质
熔点：	103-145 DEG C
注解：	APPLICATION: PRECURSOR TO A CHIRAL BRONSTED ACID (674745) USED TO CATALYZE AN ENANTIOSELECTIVE AZA DIELS-ALDER REACTION PROVIDING BICYCLIC LACTAMS. RARE EARTH METAL COMPLEXES OF THIS CHIRAL BINAPTHOL CATALYZE AN INTRAMOLECULAR HYDROAMINATION OF AMINO OLEFINS LEADING TO CHIRAL PYRROLIDINES OPTICAL ACTIVITY: [ALPHA]20/D +114 DEG, C = 1 IN CHLOROFORM UNSPSC: 12352100 WGK: 3
安全信息
WGK德国：	3

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