basic_info |
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| Product_Name： | R-α,α-双(3,5-二三氟甲基苯基)脯氨醇三甲基硅醚 |
| CAS： | 908303-26-4 |
| 中文同义词： | R-α,α-双(3,5-二三氟甲基苯基)脯氨醇三甲基硅醚 |
| EnglishSynonyms： | (R)-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-2-PYRROLIDINEMETHANOL TRIMETHYLSILYL ETHER ; (R)-2-(BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)((TRIMETHYLSILYL)OXY)METHYL)PYRROLIDINE ; (2R)-2-((3,5-BIS(TRIFLUOROMETHYL)PHENYL)(3,5-BIS(TRIFLUOROMETHYL)PHENYL)(TRIMETHYLSILYLOXY)METHYL)PYRROLIDINE ; (R)-ALPHA,ALPHA-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PROLINOL TRIMETHYLSILYL ETHER ; (R)-ALPHA,ALPHA-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-2-PYRROLIDINEMETHANOL TRIMETHYLSILYL ETHER ; (R)-2-[([BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)]TRIMETHYLSILANYLOXY)METHYL]PYRROLIDINE ; PYRROLIDINE, 2-[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL][(TRIMETHYLSILYL)OXY]METHYL]-, (2R)- |
| pro_mdlNumber： | MFCD09750448 |
| pro_acceptors： | 2 |
| pro_donors： | 1 |
| pro_smile： | C[Si](C)(C)OC(c1cc(cc(c1)C(F)(F)F)C(F)(F)F)(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)[C@H]3CCCN3 |
| InChi： | InChI=1S/C24H23F12NOSi/c1-39(2,3)38-20(19-5-4-6-37-19,13-7-15(21(25,26)27)11-16(8-13)22(28,29)30)14-9-17(23(31,32)33)12-18(10-14)24(34,35)36/h7-12,19,37H,4-6H2,1-3H3/t19-/m1/s1 |
| InChiKey： | InChIKey=MOHRGTBNEJKFMB-LJQANCHMSA-N |
property |
|
| MeltingPoint： | 46-55 DEG C |
| PhysicalProperty： | FLASHPOINT: >110 DEG C FLASHPOINT: >230 DEG F |
| Comments： | APPLICATION: CATALYST INVOLVED IN: CYCLOCONDENSATION OF ENALS WITH METHYLENEPYRROLIDINES. ORGANOCATALYTIC ADDITIONS OF BETA-KETOSULFOXIDES TO CONJUGATED ALDEHYDES. ORGANOCATALYTIC AZA-MICHAEL REACTIONS. STEREOSELECTIVE PROPARGYLIC ALKYLATION OF PROPARGYLIC ESTERS WITH ALDEHYDES. EPOXIDATION OR AZIRIDINATION OF ALPHA,BETA-UNSATURATED ALDEHYDES AND FEIST-BENARY REACTIONS OF 1,3-DICARBONYLS PROTOCOLS AND APPLICATIONS: ASYMMETRIC A-FUNCTIONALIZATION OF ALDEHYDES USING JORGENSEN'S ORGANOCATALYSTS UNSPSC: 12352100 WGK: 3 |
| Specification： | TECHNICAL GRADE |
| Information： | OPTICAL PURITY: ENANTIOMERIC EXCESS: =>99.0% (HPLC) |
secure_info |
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| secure_symbol： |
GHS07
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H315-H319-H335 |
| secure_cautionary_stmt： | P261-P305 + P351 + P338 |
| secure_damage_code： | Xi |
| secure_risk_disclosure_stmt： | R:36/37/38 |
| secure_security_stmt： | S:26 |
| secure_wgk_germany： | 3 |
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