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| Product_Name： | 2,2',2'',2'''-(1,2-PHENYLENEBIS[(1R,3R)-TETRAHYDRO-5,8-DIOXO-1H-[1,2,4]DIAZAPHOSPHOLO[1,2-A]PYRIDAZINE-2,1,3(3H)-TRIYL])TETRAKIS(N-[(1S)-1-PHENYLETHYL])BENZAMIDE |
| CAS： | 851609-33-1 |
| EnglishSynonyms： | BIS[(R,R,S)-DIAZAPHOS-SPE] ; 2,2',2'',2'''-(1,2-PHENYLENEBIS[(1R,3R)-TETRAHYDRO-5,8-DIOXO-1H-[1,2,4]DIAZAPHOSPHOLO[1,2-A]PYRIDAZINE-2,1,3(3H)-TRIYL])TETRAKIS(N-[(1S)-1-PHENYLETHYL])BENZAMIDE |
| pro_mdlNumber： | MFCD10566994 |
| pro_acceptors： | 16 |
| pro_donors： | 4 |
| pro_smile： | C[C@@H](c1ccccc1)NC(=O)c2ccccc2[C@@H]3N4C(=O)CCC(=O)N4[C@H](P3c5ccccc5P6[C@@H](N7C(=O)CCC(=O)N7[C@H]6c8ccccc8C(=O)N[C@@H](C)c9ccccc9)c1ccccc1C(=O)N[C@@H](C)c1ccccc1)c1ccccc1C(=O)N[C@@H](C)c1ccccc1 |
| InChi： | InChI=1S/C78H72N8O8P2/c1-49(53-27-9-5-10-28-53)79-71(91)57-35-17-21-39-61(57)75-83-67(87)45-46-68(88)84(83)76(62-40-22-18-36-58(62)72(92)80-50(2)54-29-11-6-12-30-54)95(75)65-43-25-26-44-66(65)96-77(63-41-23-19-37-59(63)73(93)81-51(3)55-31-13-7-14-32-55)85-69(89)47-48-70(90)86(85)78(96)64-42-24-20-38-60(64)74(94)82-52(4)56-33-15-8-16-34-56/h5-44,49-52,75-78H,45-48H2,1-4H3,(H,79,91)(H,80,92)(H,81,93)(H,82,94)/t49-,50-,51-,52-,75+,76+,77+,78+/m0/s1 |
| InChiKey： | InChIKey=NTWCWWNZWYJTEP-JMTUPYQHSA-N |
property |
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| MeltingPoint： | 183-195 DEG C |
| Comments： | APPLICATION: DIAZAPHOSPHOLANE LIGANDS DISPLAY EXCELLENT LEVELS OF CONVERSION AND SELECTIVITY IN RH-CATALYZED ASYMMETRIC HYDROFORMYLATION REACTIONS APPLICATION: DIAZAPHOSPHOLANE LIGANDS FOR CATALYTIC ASYMMETRIC TRANSFORMATIONSCATALYST FOR: ENANTIOSELECTIVE SYNTHESIS OF ALPHA,BETA-UNSATURATED ALDEHYDES VIA HYDROFORMYLATION OF DIENES. REGIOSELECTIVE AND ENANTIOSELECTIVE HYDROFORMYLATION OF DIALKYL ACRYLAMIDES. ASYMMETRIC HYDROFORMYLATION OF VINYL ACETATE. REGIOSELECTIVE AND STEREOSELECTIVE HYDROFORMYLATION OF ALKENES LEGAL INFORMATION: PRODUCT IS SOLD FOR R AND D PURPOSE ONLY AND USE BY END USER IN THE MANUFACTURE OF PRODUCTS OF COMMERCE IS NOT PERMITTED. PRODUCT IS SOLD IN ASSOCIATION WITH DOWPHARMASM A BUSINESS UNIT OF THE DOW CHEMICAL COMPANY US PAT 7,071,357B OPTICAL ACTIVITY: [ALPHA]20/D -82.0 DEG, C = 1 IN THF UNSPSC: 12352100 WGK: 3 |
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English![2,2',2'',2'''-(1,2-PHENYLENEBIS[(1R,3R)-TETRAHYDRO-5,8-DIOXO-1H-[1,2,4]DIAZAPHOSPHOLO[1,2-A]PYRIDAZINE-2,1,3(3H)-TRIYL])TETRAKIS(N-[(1S)-1-PHENYLETHYL])BENZAMIDE](http://www.chemcd.com/createImage?smile=C%5BC%40%40H%5D%28c1ccccc1%29NC%28%3DO%29c2ccccc2%5BC%40%40H%5D3N4C%28%3DO%29CCC%28%3DO%29N4%5BC%40H%5D%28P3c5ccccc5P6%5BC%40%40H%5D%28N7C%28%3DO%29CCC%28%3DO%29N7%5BC%40H%5D6c8ccccc8C%28%3DO%29N%5BC%40%40H%5D%28C%29c9ccccc9%29c1ccccc1C%28%3DO%29N%5BC%40%40H%5D%28C%29c1ccccc1%29c1ccccc1C%28%3DO%29N%5BC%40%40H%5D%28C%29c1ccccc1&size=web.jpg)