[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE ,215597-19-6

[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE

CAS号: 215597-19-6 ;191654-69-0
CCD编号: CCD01268525
分子式: C48 H40 P2 . Cl2 Pd
分子量: 856.118

基本信息
产品名称：	[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
CAS：	215597-19-6 ;191654-69-0
英文同义词：	PALLADIUM, [(1S)-[1,1'-BINAPHTHALENE]-2,2'-DIYLBIS[BIS(4-METHYLPHENYL)PHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)- ; [(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE ; [PDCL2[(R)-4-TOLYLBINAP]] ; [(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE ; [PDCL2[(S)-4-TOLYLBINAP]]
MDL号：	MFCD11656205
氢键受体数量：	0
氢键供体数量：	0
Smile：	Cc1ccc(cc1)P(c2ccc(cc2)C)c3ccc4ccccc4c3c5c6ccccc6ccc5P(c7ccc(cc7)C)c8ccc(cc8)C.Cl[Pd]Cl
InChi：	InChI=1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2
InChiKey：	InChIKey=ADMKISPNGKUJAU-UHFFFAOYSA-L
性质
熔点：	>300 DEG C
注解：	APPLICATION: CATALYST FOR: ENANTIOSELECTIVE PREPARATION OF HYDROXYDICARBONYLS VIA ALDOL ADDITION OF PYRUVATES AND DIKETONES WITH KETENE THIOACETAL STEREOSELECTIVE ALDOL CONDENSATION USING TRIMETHYL[[(PHENYL)ETHENYL]OXY]SILANE AND BENZALDEHYDE AS REACTANTS STEREOSELECTIVE PREPARATION OF NAPHTHALENOLS VIA ALKYLATIVE RING OPENING OF OXABENZONORBORNADIENES WITH DIALKYLZINC REACTANT FOR: PREPARATION OF PALLADIUM BIS(DIPHENYLPHOSPHINO)BINAPHTHYL AQUA MONONUCLEAR AND HYDROXO-BRIDGED DINUCLEAR COMPLEXES WGK: 3
安全信息
符号：	GHS07
信号词：	Warning
危险声明：	H302 + H312 + H332-H315-H319-H335
警示性声明：	P261-P280-P305 + P351 + P338
危害码：	Xn
风险声明：	R:20/21/22-36/37/38
安全声明：	S:26
WGK德国：	3

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[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE

基本信息

性质

安全信息

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