basic_info |
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| Product_Name： | (11BR)-2,6-DI-9-PHENANTHRENYL-4-HYDROXY-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE |
| CAS： | 1043567-32-3 ;864943-22-6 |
| EnglishSynonyms： | (R)-3,3'-BIS(9-PHENANTHRYL)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE ; (R)-3,3'-BIS(9-PHENANTHRYL)-1,1'-BINAPHTHYL 2,2'-DIYL HYDROGENPHOSPHATE ; (S)-3,3'-BIS(9-PHENANTHRYL)-1,1'-BINAPHTHYL 2,2'-DIYL HYDROGENPHOSPHATE ; (11BR)-2,6-DI-9-PHENANTHRENYL-4-HYDROXY-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE |
| pro_mdlNumber： | MFCD12546016 |
| pro_acceptors： | 4 |
| pro_donors： | 1 |
| pro_smile： | c1ccc2c(c1)cc(c3c2cccc3)c4cc5ccccc5c-6c4OP(=O)(Oc7c6c8ccccc8cc7c9cc1ccccc1c1c9cccc1)O |
| InChi： | InChI=1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50) |
| InChiKey： | InChIKey=BVICVEIKBNVROI-UHFFFAOYSA-N |
property |
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| MeltingPoint： | 390-400 DEG C |
| Comments： | APPLICATION: CATALYST FOR: ASYMMETRIC HYDROGENATION CASCADE. ENANTIOSELECTIVE FRIEDEL-CRAFTS REACTION. ASYMMETRIC HYDROGENATION OF 2-SUBSTITUTED QUINOLINES. CHIRAL BROENSTED ACID CATALYZED ENANTIOSELECTIVE A-AMINOXYLATION OF ENE CARBAMATES. PREPARATION OF BETA-CARBOLINES VIA DIASTEREO- AND ENANTIOSELECTIVE N-ACYLIMINIUM CYCLIZATION CASCADES OF TRYPTAMINES AND KETO ACIDS/ESTERS. ASYMMETRIC TRANSFER HYDROGENATION OF SUBSTITUTED QUINOXALINES OPTICAL ACTIVITY: [ALPHA]22/D -44.0 DEG, C = 1 IN DMSO STORAGE TEMPERATURE: -20 DEG C WGK: 3 |
secure_info |
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| secure_wgk_germany： | 3 |
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English![(11BR)-2,6-DI-9-PHENANTHRENYL-4-HYDROXY-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE](http://www.chemcd.com/createImage?smile=c1ccc2c%28c1%29cc%28c3c2cccc3%29c4cc5ccccc5c-6c4OP%28%3DO%29%28Oc7c6c8ccccc8cc7c9cc1ccccc1c1c9cccc1%29O&size=web.jpg)