basic_info |
|
| Product_Name： | (-)-B-甲氧基二异松莰基硼烷 |
| CAS： | 85134-98-1 ;99438-28-5 |
| 中文同义词： | (+)- B -甲氧基二异松莰基硼烷 ; (-)-B-甲氧基二异松莰基硼烷 |
| EnglishSynonyms： | (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE HYDRATE 97+% ; (+)-DIISOPINOCAMPHEYLMETHOXYBORANE ; (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE ; (+)-BETA-METHOXYDIISOPINOCAMPHEYL-BORANE |
| pro_mdlNumber： | MFCD21332906 |
| pro_acceptors： | 1 |
| pro_donors： | 0 |
| pro_smile： | B([C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C)([C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C)OC |
| InChi： | InChI=1S/C21H37BO/c1-12-16-8-14(20(16,3)4)10-18(12)22(23-7)19-11-15-9-17(13(19)2)21(15,5)6/h12-19H,8-11H2,1-7H3/t12-,13-,14+,15+,16-,17-,18-,19-/m0/s1 |
| InChiKey： | InChIKey=IAQXEQYLQNNXJC-JPDDNCELSA-N |
property |
|
| PhysicalProperty： | FLASHPOINT: 113 DEG C FLASHPOINT: 235.4 DEG F |
| Comments： | APPLICATION: BOTH (+)- AND (-)-FORMS ARE PRECURSORS TO B-ALLYLDIISOPINOCAMPHEYLBORANE DERIVATIVES, WHICH ARE SUBSEQUENTLY REACTED WITH ALDEHYDES TO GIVE HOMOALLYLIC ALCOHOLS AND BETA-AMINO ALCOHOLS OF HIGH ENANTIOMERIC EXCESS APPLICATION: REACTANT INVOLVED IN: OXIDATIVE CYCLIZATION AND ALKYLATION FOR SYNTHESIS OF IONOMYCIN. INTRAMOLECULAR CONJUGATE ADDITION FOR TETRAHYDROPYRAN SYNTHESIS. ALDOL ADDITION AND SUZUKI COUPLING REACTIONS. ALLYLATION. SYNTHESIS OF ALKANOLS UNSPSC: 12352100 WGK: 3 |
secure_info |
|
| secure_symbol： |
GHS07
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H315-H319-H335 |
| secure_cautionary_stmt： | P261-P305 + P351 + P338 |
| secure_damage_code： | Xi |
| secure_risk_disclosure_stmt： | R:36/37/38 |
| secure_security_stmt： | S:26-36 |
| secure_wgk_germany： | 3 |
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